bcmubx2107 – Capacitive sensor based on Metal Organic Frameworks for volatile organic compounds detection
Poster-EFernandezAbstract
We evaluate the potential of 2D printing technologies to create thin film gas sensors from ionic liquid (IL)/metal-organic framework (MOF) composites. To accomplish this, we synthesized the MOF solvothermally then impregnated it with the IL. The structure and basic properties of the IL/MOF composites were characterized using thermal, spectroscopic and X-ray diffraction techniques, and the resultant sensing capacity of the bulk material was evaluated by impedance spectroscopy. The IL/MOF systems were then integrated into a 2D printed silver capacitive circuit by spray and tested on a custom-made gas flow apparatus. Exposure of the IL/MOF based sensors to water, acetone and ethanol induces a repetitive variation of the capacitance (from 0.05 to 7 pico-Farads) that is dependent on the nature of the gas. IL/MOF based sensors can detect changes in concentrations in the range of 10k-100k ppm in less than a second. Such materials offer countless possibilities to tailor the porosity, chemistry, selectivity, and electrical response to make the sensor suitable to detect the desired analyte.